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Waste Water Treatment by Liquid-Solid Adsorption Using Calcined Sand-Clay Mixture Adsorbent

Iraqi Journal of Chemical and Petroleum Engineering

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Title Waste Water Treatment by Liquid-Solid Adsorption Using Calcined Sand-Clay Mixture Adsorbent
 
Creator ALmilly, Raghad F.
Hasan, Mohanned H.
 
Description Effluent from incompetent wastewater treatment plants (WWTPs) contains a great variety of pollutants so support water treatments are essential. The present work studies the removal of phosphate species from aqueous solutions by adsorption on to spherical Calcined Sand -Clay mixture (CSCM) used a natural, local and low-cost adsorbent. Batch experiments were performed to estimate removal efficiency of phosphate. The adsorption experiments were carried out as function of pH, dose of adsorbent, initial concentration, temperature and time of adsorption. The efficient removal was accomplished for pH between 10 and 12. The experimental results also showed that the removal of phosphate by (CSCM) was rapid (the % removal 98.9%, 92%, 90%, 89% in 60 min) when the initial phosphate concentrations were at  5, 10, 15, 20 mg/l, respectively at optimum PH 10-12 and optimum dose was 5 gm/200ml.   The adsorption process is time dependent. Thermodynamic studies showed that phosphate adsorption was exothermic. The effect of temperature range of 15-30 °C has been investigated. The results indicated that the temperature significantly affected phosphate adsorption on (CSCM)  adsorbent. Langmuir and Freundlich  isotherms models indicated that both isotherms were proper to describe the adsorption characteristics of (CSCM), with Langmuir being more fit.  Adsorption capacity of phosphate had equal to 0.835 mg phosphorous/g adsorbent. The study reveal that calcined sand-clay mixture is an excellent low cost material for phosphate removal in wastewater treatment process .
 
Publisher University of Baghdad/ College of Engineering
 
Date 2017-06-30
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
 
Format application/pdf
 
Identifier http://ijcpe.uobaghdad.edu.iq/index.php/ijcpe/article/view/204
 
Source Iraqi Journal of Chemical and Petroleum Engineering; Vol 18 No 2 (2017): Iraqi Journal of Chemical and Petroleum Engineering; 69-81
المجلة العراقية للهندسة الكيمياوية وهندسة النفط; مجلد 18 عدد 2 (2017): Iraqi Journal of Chemical and Petroleum Engineering; 69-81
2618-0707
1997-4884
 
Language eng
 
Relation http://ijcpe.uobaghdad.edu.iq/index.php/ijcpe/article/view/204/200