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Removal of Direct 50 Dyes from Aqueous Solution Using Natural Clay and Organoclay Adsorbents

Baghdad Science Journal

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Title Removal of Direct 50 Dyes from Aqueous Solution Using Natural Clay and Organoclay Adsorbents
 
Creator Journal, Baghdad Science
 
Description In this study, hexadecyltrimethylammonium bromide (HDMAB) - bentonite was synthesized by placing alkylammonium cation onto bentonite. Adsorption of textile dye such as direct Yellow 50 on natural bentonite and HDMAB -bentonite was investigated. The effects of pH, contact time,dosage clay and temperature were investigated experimentally .The Langmuir and Freundlish isotherms equations were applied to the data and values of parameters of these isotherm equations were evaluated. The study indicated that using 0.2 g of HDMAB (hexadecyltrimethylammonium bromide) lead to increase the percentage removal(R%) from 78% for pure bentonite to 99 %. The optimum pH value for the adsorption experiments was found to be pH=3 and therefore all the experiments were carried out at this pH value. The pseudo-second-order kinetic model agrees very well with the experimental results.Different thermodynamic parameters such as Gibb’s free energy, enthalpy and entropy of the on-going adsorption process have also been evaluated. The thermodynamic analyses of the dye adsorption on organoclay indicated that the system was endothermic in nature .
 
Publisher College of Science for Women - University of Baghdad
 
Date 2015-03-01
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Peer-reviewed Article
 
Format application/pdf
 
Identifier http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/537
 
Source مجلة بغداد للعلوم; مجلد 12 عدد 1 (2015): issue 1; 157-166
Baghdad Science Journal; Vol 12 No 1 (2015): issue 1; 157-166
2411-7986
2078-8665
 
Language eng
 
Relation http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/537/468
 
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